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Antimony is an element with an interesting
history and properties. For a long time people have been using that wide enough.
The element is required at both: technical field and culture development.
According to historians the first production of
antimony was found at Ancient East 5 thousand years ago.
History
of Antimony
Besides gold, mercury, copper and other six
elements, antimony is considered like a prehistoric element. Unfortunately the
name of antimony discoverer is unknown. But is well known vessels were made of
antimony in Babylon 3000 years B.C. Latin name of the element «stibium» occurs
at works of Pliniy Sr. It descends from Greek «στιβι». Originally it denoted not an antimony metal
but prolate mineral of antimony glance.
In ancient
Europe people knew only antimony glance and start producing antimony regulus
which was considered as semimetal. According to the Middle Ages prominent
scientist at metal manufacturing Agricola: “When the certain portion of antimony
is alloyed with the lead it results in the type alloy. It’s used by book
printers.” Thus the element ¹51 is
applied in printing for ages.
For the
first time methods of antimony
refining and antimony properties, antimony compounds and alloys were described
at a famous book «Triumphal car of Antimony» in 1604. The author referred needle
antimony to as “Antimony”. It was descended from the Greek “ανεμον” – flower (as needle antimony
crystals look like a composite flower).
The name “ANTIMONY” defined only
this mineral very long time in Russia and overseas. Antimony metal was defined
as regulus antimony (regulus antimoni). In 1789 Louvuosier included antimony at
the list of elementary substances and called it “antimonie”. Now this name
remains in French language as the name of the element ¹ 51. English and German
names of this element are also similar - Antimony, Antimon.
But there
is another version. According to that version the Superior of the abbey in
Schtalgausen drew his attention to a very good state of health of the pigs,
which licked “dark substance with metallic lustre” and decided to mix that into
the monks meal. Forty monks died in the throes.
Since that
the substance got the name “antimonium”, i.e. substance “anti” “monks” (in full
see “Life stone” by Y. Gashek).
Russian
name of the element “sur’ma” descends from Turkish “s’urme”, translated as
“rubbing” or “darkening” of brows. Till 19th century the expression “eyebrows
darkening” existed, though it was made with antimony compounds not always. The
only antimony compound was used as eyebrow-dye – black modification of
trisulfide antimony. So that first it was denoted by the word, which became the
Russian name of element ¹ 51.
What is it for?
Antimony metal is used very seldom because of
its shortness. But metallurgists often add antimony into alloys as it
strengthens solidity of other metals (tin, lead) and doesn’t oxidize in usual
environment. The number of alloys containing antimony is near to 200. The most
famous antimony alloys are antimony lead, type metal, bearing
metal.
Bearing metals are alloys with tin, lead and
copper, sometimes with zinc and bismuth.
This alloys are comparatively fustible and used
in bearing brasses production by casting.
The most common-used alloys of this group are babbits containing 4-15 %
of antimony.
Babbits are used in machine-tool construction,
railway transport, motor transport. Bearing metals have considerable strength,
fatigue resistance, corrosion resistance.
Antimony is the one of a number of metals that
dilate when consolidating. Because of that type metal (alloy containing lead
(82%), tin (3%) and antimony (15%) casting very well in moulds to produce
prints; prints made of this alloy let to reach clear imprints.
Antimony increases strength and percussion
stability.
Lead alloyed with antimony (5 – 15%) is called
antimony lead. 1% addition of antimony increases lead strength substantially.
Antimony lead is used in chemical engineering, corrosive liquid pipes
production, electric, telegraph, telephone cables sheathing production,
electrodes and lead-acid battery grids production. Lead-acid secondary batteries
are the largest metallurgical market for the element ¹54. Also antimony is used
in lead alloy shot and ammunition.
Antimony compounds are also applied widely in
engineering. Antimony trisulphide is used in matches and fireworks production.
Most of antimony materials are made of antimony trisulphide. Antimony pentasulphide is used in
vulcanization of rubber. Red medical rubber containing antimony pentasulphide is
very flexible. Heat resistant antimony trioxide is used in flame retardant
paints, construction materials, textiles, conveyor belts, enamels.
High-purity
antimony metal is used in the production of intermetallic compound semiconductor
materials such as indium antimonide, aluminium antimonide and gallium
antimonide. Antimony is used as a doping agent for one of the most important
semiconductors – germanium.
Hydrated
potassium antimonyl tartar, known as tartar emetic, is used in medicines for the
treatment of stomach ailments. The
chemical, together with the less toxic organic antimonides – ethylstibamine,
sodium antimonyl gluconate (Pentostam) and N-methylglucamine antimonate
(Glucantime) – have been used to treat leishmaniasis, a disease transmitted by
sandflies.
A lot of
antimony compounds are used as pigments in pants production.
So antimony
is one of the oldest metal known on the one hand and a very required one n the
other.
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